Intramolecular cyclization of a diruthenium complex: insight into the mechanism of heteroatom-directed intramolecular C-H/olefin coupling reactions.
نویسندگان
چکیده
Complex 2, synthesized by the reaction of {(C5H4N)(μ2-η(5):η(1)-C9H5)}Ru3(CO)9 (1) with 1,5-hexadiene, could further transform to another diruthenium complex 3via intramolecular carbometalation. The results are relevant to the mechanism of transition-metal catalyzed heteroatom-directed intramolecular C-H/olefin coupling reactions.
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عنوان ژورنال:
- Dalton transactions
دوره 44 28 شماره
صفحات -
تاریخ انتشار 2015